@Ben First off - welcome to the Rockstor community forum.
As btrfs’s raid works at the chunk level and it’s current implementation of raid1 is 2 way not n-way, you can’t define what you are after, assuming you are specifying a 3-way raid 1 (at the lower level): ie 3 copies of everything. Btrfs raid 1 only does 2 copies on 2 different devices and btrfs raid 10 is, as you indicate, a stripe over 2 or more raid1(2-way) mirrored drives(at the chunk level). So note that if you have 3 drives in btrfs raid1, one chunk may be on drive 1 and 2 while another chunk may be on drive 2 and 3 so chunk not drive level of raid.
@Spectre694 does a nice explanation of btrfs raid levels and capabilities in the following thread started by @Bayonet:
Afraid not regardless of what you do BTRFS RAID 1 is a 2 way setup and it isn’t possible to do n-way. The only way to be able to survive a two disk failure with BTRFS is by using RAID 6. HOWEVER BTRFS’s RAID 5/6 has been found to have multiple severe bugs and cannot be recommended at the moment.