@robnicholson welcome to the Rockstor community. It looks like you ran into similar problems as have been reported on the forum previously.
There is an open issue for this particular challenge, especially when using the /24 address format, I believe.
Take a look here:
And there is a corresponding issue on github, which, unfortunately, has not been resolved yet.:
So using nmcli or 'nmtui is currently probably the best choice in that space for now.
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